Cylinders and pressure drums shall be so filled that at 50ºC the non-gaseous phase does not exceed 95% of their water capacity and they are not completely filled at 60ºC. When filled, the internal pressure at 65ºC shall not exceed the test pressure of the cylinders and pressure drums. The vapour pressures and volumetric expansion of all substances in the cylinders and pressure drums shall be taken into account. For liquids charged with a compressed gas both components – the liquid and the compressed gas – have to be taken into consideration in the calculation of the internal pressure in the pressure receptacle. When experimental data is not available, the following steps shall be carried out:
(a) calculation of the vapour pressure of the liquid and of the partial pressure of the compressed gas at 15°C (filling temperature);
(b) calculation of the volumetric expansion of the liquid phase resulting from the heating from 15°C to 65°C and calculation of the remaining volume for the gaseous phase;
(c) calculation of the partial pressure of the compressed gas at 65°C considering the volumetric expansion of the liquid phase;
Note: The compressibility factor of the compressed gas at 15°C and 65°C shall be considered.
(d) calculation of the vapour pressure of the liquid gas at 65°C;
(e) the total pressure is the sum of the vapour pressure of the liquid gas and the partial pressure of the compressed gas at 65°C;
(f) consideration of the solubility of the compressed gas at 65°C in the liquid phase.
The test pressure of the cylinders or pressure drums shall not be less than the calculated total pressure minus 100 kPa (1bar).
If the solubility of the compressed gas in the liquid phase is not known for the calculation, the test pressure can be calculated without taking the gas solubility (subparagraph (f)) into account.